Author
Ramyar, K., Felekoglu, B., Mardani, A., Kobya, V., Karakuzu, Kemal
Publication Date
2024-07-01
Publication Place
-
ASCE
Subject
C(3)A, Cement-admixture compatibility, Rheology, Anionic groups, Adsorption, Polycarboxylate ether (PCE)
Type
Periodical
Language
English
Digital
Yes
Manuscript
No
Library
Özyeğin University
Library Asset ID
0899-1561
Record ID
da04cc97-43f4-4d38-9ef4-c508ee4c0725
Date
2024-07-01
Notes
TÜBİTAK ; Ministry of National Education - Turkey
Sample Text
In this study, the performances of methylallyl ether (HPEG) type polycarboxylate ether-based water reducing admixtures (PCE) partially substituted with phosphate and sulfonate anionic groups were investigated. The effects of synthesized PCE's on the fresh, rheological, and some hardened properties of mixtures prepared with cements having different C(3)A contents were examined. Increasing the phosphate and sulfonate substitution ratio of PCE up to a certain value improved the rheological properties of the mixtures. Best flow retention and rheological properties were obtained with 9% phosphate (P9) and 7% sulfonate (S7) PCEs. Due to the high PCE dosage used in the Marsh-funnel and mini slump experiments, the nonadsorbed PCE in the pore solution blocked the adsorbed polymers on the cement particles. Also, the hydrodynamic radius of the polymer had a significant effect on the adsorption and dispersion performance of PCE. Morover, with the increase of cement C(3)A content, the fresh properties of the mixtures were adversely affected. However, the increase in C(3)A content up to a certain value improved the hardened properties of the cementitious system. (c) 2024 American Society of Civil Engineers.
DOI
10.1061/JMCEE7.MTENG-16601
Cilt
36
