Cationic metal-organic frameworks synthesized from cyclotetraphosphazene linkers with flexible tentacles

Name: Cationic metal-organic frameworks synthesized from cyclotetraphosphazene linkers with flexible tentacles
Author: Davarcı, D., Fındıkçı, İlknur Eruçar, Yücesan, G., Zorlu, Y.

İsim	Cationic metal-organic frameworks synthesized from cyclotetraphosphazene linkers with flexible tentacles
Yazar	Davarcı, D., Fındıkçı, İlknur Eruçar, Yücesan, G., Zorlu, Y.
Basım Tarihi:	2022-12-07
Basım Yeri	- American Chemical Society
Tür	Süreli Yayın
Dil	İngilizce
Dijital	Evet
Yazma	Hayır
Kütüphane:	Özyeğin Üniversitesi
Demirbaş Numarası	1528-7483
Kayıt Numarası	53b64d4c-257c-4ec8-a390-f3f4bddc4d3b
Lokasyon	Natural and Mathematical Sciences
Tarih	2022-12-07
Notlar	Türkiye Bilimler Akademisi
Örnek Metin	Metal-organic frameworks (MOFs) based on group 12 metals, namely, [Zn2(O3PyCP)Cl4] (Zn-O3PyCp), [Cd(O3PyCP)(NO3)2].H2O (Cd-O3PyCp), and [Hg(O3PyCP)Cl2] (Hg-O3PyCp), were synthesized using a novel flexible molecular building block, octakis(3-pyridyloxy)cyclotetraphosphazene (O3PyCP), and group 12 metal salts (ZnCl2, Cd(NO3)2.6H2O, and HgCl2). The crystals of each of the cationic frameworks were structurally characterized by single-crystal X-ray diffraction, Fourier transform infrared, and thermogravimetric analysis. Because of the flexibility of the O3PyCP building block, we were able to observe three distinct cationic frameworks with group 12 metal ions. We performed the atomically detailed simulations to compute H2 adsorption isotherms of the resulting frameworks at a pressure range of 0-1 bar at 77 K. Zn-O3PyCp exhibits the highest H2 uptake capacity (58.42 cm3 STP/g).
DOI	10.1021/acs.cgd.2c00806
Cilt	22

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Cationic metal-organic frameworks synthesized from cyclotetraphosphazene linkers with flexible tentacles

Yazar Davarcı, D., Fındıkçı, İlknur Eruçar, Yücesan, G., Zorlu, Y.

Basım Tarihi 2022-12-07

Basım Yeri - American Chemical Society

Tür Süreli Yayın

Dil İngilizce

Dijital Evet

Yazma Hayır

Kütüphane Özyeğin Üniversitesi

Demirbaş Numarası 1528-7483

Kayıt Numarası 53b64d4c-257c-4ec8-a390-f3f4bddc4d3b

Lokasyon Natural and Mathematical Sciences

Tarih 2022-12-07

Notlar Türkiye Bilimler Akademisi

Örnek Metin Metal-organic frameworks (MOFs) based on group 12 metals, namely, [Zn2(O3PyCP)Cl4] (Zn-O3PyCp), [Cd(O3PyCP)(NO3)2].H2O (Cd-O3PyCp), and [Hg(O3PyCP)Cl2] (Hg-O3PyCp), were synthesized using a novel flexible molecular building block, octakis(3-pyridyloxy)cyclotetraphosphazene (O3PyCP), and group 12 metal salts (ZnCl2, Cd(NO3)2.6H2O, and HgCl2). The crystals of each of the cationic frameworks were structurally characterized by single-crystal X-ray diffraction, Fourier transform infrared, and thermogravimetric analysis. Because of the flexibility of the O3PyCP building block, we were able to observe three distinct cationic frameworks with group 12 metal ions. We performed the atomically detailed simulations to compute H2 adsorption isotherms of the resulting frameworks at a pressure range of 0-1 bar at 77 K. Zn-O3PyCp exhibits the highest H2 uptake capacity (58.42 cm3 STP/g).

DOI 10.1021/acs.cgd.2c00806

Cilt 22