Hydrothermal synthesis and characterization of two dimensional coordination polymers with 2,2′-dimethylglutarate and 1,2-bis(imidazol-1-ylmethyl)benzene

Name: Hydrothermal synthesis and characterization of two dimensional coordination polymers with 2,2′-dimethylglutarate and 1,2-bis(imidazol-1-ylmethyl)benzene
Author: Yaman, P. K., Erer, H., Arici, M., Fındıkçı, İlknur Eruçar, Yesilel, O. Z.

İsim	Hydrothermal synthesis and characterization of two dimensional coordination polymers with 2,2′-dimethylglutarate and 1,2-bis(imidazol-1-ylmethyl)benzene
Yazar	Yaman, P. K., Erer, H., Arici, M., Fındıkçı, İlknur Eruçar, Yesilel, O. Z.
Basım Tarihi:	2019-03-24
Basım Yeri	- Elsevier
Konu	Coordination polymers, Hydrothermal synthesis method, 2,2′-Dimethylglutarate complex, 1,2-Bis(imidazol-1-ylmethyl)benzene
Tür	Süreli Yayın
Dil	İngilizce
Dijital	Evet
Yazma	Hayır
Kütüphane:	Özyeğin Üniversitesi
Demirbaş Numarası	0020-1693
Kayıt Numarası	dfa4352b-62f0-4536-aad3-eed38e628f43
Lokasyon	Mechanical Engineering
Tarih	2019-03-24
Notlar	BIDEP Tubitak-2218 post-doctoral research scholarship ; Turkish Academy of Sciences
Örnek Metin	The hydrothermal reactions of some metal ions with 2,2'-dimethylglutaric acid (22dmgH(2)) and 1,2-bis(imidazol-1-ylmethyl)benzene (obix) newly afford four coordination polymers are called, {[Co-2 (mu-22dmg)(2)(mu-obix)(2)]center dot 1.5H(2)O}(n) (1), {[Cu(mu-22dmg)(mu-obix)]center dot H2O}(n) (2), {[Zn-2(mu-22dmg)(2)(mu-obix)(2)]center dot 2H(2)O}(n) (3) and [Cd-2(mu-22dmg)(2)(mu-obix)(2)(H2O)](n) (4). All of the complexes were characterized by elemental analysis, IR spectra, single crystal X- ray diffraction, powder X-ray diffraction (PXRD), and thermal analysis techniques. Furthermore, photoluminescence and topological properties were studied. The X-ray single crystal study shows that complexes 1, 3 and 4 display 3-fold parallel interpenetrating networks with hcb topology showing an unusual 2D + 2D + 2D -> 2D structures. Topological analysis reveals that complex 2 has an uninodal 4-c net sql topology with the point symbol of 4(4).6(2). Atomically-detailed simulations were finally performed to compute hydrogen (H-2) uptake in these complexes at 77 K.
DOI	10.1016/j.ica.2018.12.039
Cilt	488

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Hydrothermal synthesis and characterization of two dimensional coordination polymers with 2,2′-dimethylglutarate and 1,2-bis(imidazol-1-ylmethyl)benzene

Yazar Yaman, P. K., Erer, H., Arici, M., Fındıkçı, İlknur Eruçar, Yesilel, O. Z.

Basım Tarihi 2019-03-24

Basım Yeri - Elsevier

Konu Coordination polymers, Hydrothermal synthesis method, 2,2′-Dimethylglutarate complex, 1,2-Bis(imidazol-1-ylmethyl)benzene

Tür Süreli Yayın

Dil İngilizce

Dijital Evet

Yazma Hayır

Kütüphane Özyeğin Üniversitesi

Demirbaş Numarası 0020-1693

Kayıt Numarası dfa4352b-62f0-4536-aad3-eed38e628f43

Lokasyon Mechanical Engineering

Tarih 2019-03-24

Notlar BIDEP Tubitak-2218 post-doctoral research scholarship ; Turkish Academy of Sciences

Örnek Metin The hydrothermal reactions of some metal ions with 2,2'-dimethylglutaric acid (22dmgH(2)) and 1,2-bis(imidazol-1-ylmethyl)benzene (obix) newly afford four coordination polymers are called, {[Co-2 (mu-22dmg)(2)(mu-obix)(2)]center dot 1.5H(2)O}(n) (1), {[Cu(mu-22dmg)(mu-obix)]center dot H2O}(n) (2), {[Zn-2(mu-22dmg)(2)(mu-obix)(2)]center dot 2H(2)O}(n) (3) and [Cd-2(mu-22dmg)(2)(mu-obix)(2)(H2O)](n) (4). All of the complexes were characterized by elemental analysis, IR spectra, single crystal X- ray diffraction, powder X-ray diffraction (PXRD), and thermal analysis techniques. Furthermore, photoluminescence and topological properties were studied. The X-ray single crystal study shows that complexes 1, 3 and 4 display 3-fold parallel interpenetrating networks with hcb topology showing an unusual 2D + 2D + 2D -> 2D structures. Topological analysis reveals that complex 2 has an uninodal 4-c net sql topology with the point symbol of 4(4).6(2). Atomically-detailed simulations were finally performed to compute hydrogen (H-2) uptake in these complexes at 77 K.

DOI 10.1016/j.ica.2018.12.039

Cilt 488