Zinc(II) and cadmium(II) coordination polymers containing phenylenediacetate and 4,4′-azobis(pyridine) ligands: Syntheses, structures, dye adsorption properties and molecular dynamics simulations

Name: Zinc(II) and cadmium(II) coordination polymers containing phenylenediacetate and 4,4′-azobis(pyridine) ligands: Syntheses, structures, dye adsorption properties and molecular dynamics simulations
Author: Sezer, G. G., Arıcı, M., Fındıkçı, İlknur Eruçar, Yeşilel, O. Z., Özel, H. U., Gemici, B. T., Erer, H.

İsim	Zinc(II) and cadmium(II) coordination polymers containing phenylenediacetate and 4,4′-azobis(pyridine) ligands: Syntheses, structures, dye adsorption properties and molecular dynamics simulations
Yazar	Sezer, G. G., Arıcı, M., Fındıkçı, İlknur Eruçar, Yeşilel, O. Z., Özel, H. U., Gemici, B. T., Erer, H.
Basım Tarihi:	2017
Basım Yeri	- Elsevier
Konu	Coordination polymers, 4,4′-azobis(pyridine), Hydrothermal synthesis, Zinc(II) complex, Cadmium(II) complex, Methylene blue
Tür	Süreli Yayın
Dil	İngilizce
Dijital	Evet
Yazma	Hayır
Kütüphane:	Özyeğin Üniversitesi
Demirbaş Numarası	0022-4596
Kayıt Numarası	3caae8e8-503a-45a7-bbdf-a5a2a451f18c
Lokasyon	Natural and Mathematical Sciences
Tarih	2017
Notlar	Due to copyright restrictions, the access to the full text of this article is only available via subscription.
Örnek Metin	Two new coordination polymers (CPs) – [Zn(µ4-ppda)(µ-abpy)0.5]n(1) and [Cd(μ3-opda)(µ-abpy)0.5(H2O)]n(2) (o/ppda = 1,2/1,4-phenylenediacetate, abpy = 4,4′-azobis(pyridine)) – have been synthesized by using Zn(II)/Cd(II) salts in the presence of o- and p-phenylenediacetic acid and abpy under hydrothermal conditions. Their structures have been characterized by FT-IR spectroscopy, elemental analysis, X-ray powder diffraction and single crystal X-ray diffraction techniques. The structural diversities were observed depending on anionic ligands and metal centers in the synthesized complexes. Complex 1 consists of a 2-fold interpenetrated 3D+3D→3D framework with pcu topology while complex 2 has a 2D structure with sql topology. The adsorption of methylene blue (MB) was studied to examine the potential of the title CPs for removal of dyes from aqueous solution. Molecular dynamics (MD) simulations were also performed to examine diffusion of MB in 1 and 2. Thermal and optical properties of two complexes were also discussed.
DOI	10.1016/j.jssc.2017.08.002
Cilt	255

Kaynağa git Özyeğin Üniversitesi

Aramaya Dön

Özyeğin Üniversitesi

Kaynağa git

Zinc(II) and cadmium(II) coordination polymers containing phenylenediacetate and 4,4′-azobis(pyridine) ligands: Syntheses, structures, dye adsorption properties and molecular dynamics simulations

Yazar Sezer, G. G., Arıcı, M., Fındıkçı, İlknur Eruçar, Yeşilel, O. Z., Özel, H. U., Gemici, B. T., Erer, H.

Basım Tarihi 2017

Basım Yeri - Elsevier

Konu Coordination polymers, 4,4′-azobis(pyridine), Hydrothermal synthesis, Zinc(II) complex, Cadmium(II) complex, Methylene blue

Tür Süreli Yayın

Dil İngilizce

Dijital Evet

Yazma Hayır

Kütüphane Özyeğin Üniversitesi

Demirbaş Numarası 0022-4596

Kayıt Numarası 3caae8e8-503a-45a7-bbdf-a5a2a451f18c

Lokasyon Natural and Mathematical Sciences

Tarih 2017

Notlar Due to copyright restrictions, the access to the full text of this article is only available via subscription.

Örnek Metin Two new coordination polymers (CPs) – [Zn(µ4-ppda)(µ-abpy)0.5]n(1) and [Cd(μ3-opda)(µ-abpy)0.5(H2O)]n(2) (o/ppda = 1,2/1,4-phenylenediacetate, abpy = 4,4′-azobis(pyridine)) – have been synthesized by using Zn(II)/Cd(II) salts in the presence of o- and p-phenylenediacetic acid and abpy under hydrothermal conditions. Their structures have been characterized by FT-IR spectroscopy, elemental analysis, X-ray powder diffraction and single crystal X-ray diffraction techniques. The structural diversities were observed depending on anionic ligands and metal centers in the synthesized complexes. Complex 1 consists of a 2-fold interpenetrated 3D+3D→3D framework with pcu topology while complex 2 has a 2D structure with sql topology. The adsorption of methylene blue (MB) was studied to examine the potential of the title CPs for removal of dyes from aqueous solution. Molecular dynamics (MD) simulations were also performed to examine diffusion of MB in 1 and 2. Thermal and optical properties of two complexes were also discussed.

DOI 10.1016/j.jssc.2017.08.002

Cilt 255